Batteries in Electrochemistry

Understanding how chemical energy transforms into electrical energy using redox reactions.


What Is a Battery?

Batteries are electrochemical devices that convert chemical energy into electrical energy. This is achieved through redox (reduction-oxidation) reactions involving the transfer of electrons between two electrodes.

Basic Components of a Battery

ComponentFunction
AnodeUndergoes oxidation (loses electrons)
CathodeUndergoes reduction (gains electrons)
ElectrolyteAllows ion flow between electrodes
SeparatorPrevents contact between anode and cathode

1. Primary Batteries (Single-use)

These are non-rechargeable batteries. Once the chemical reactions are complete, they cannot be reversed.

  • Dry Cell: Zinc (anode), MnO₂ (cathode), NH₄Cl paste (electrolyte)
  • Alkaline Battery: Uses KOH electrolyte; longer life than dry cells

Applications: Remote controls, toys, flashlights

2. Secondary Batteries (Rechargeable)

These batteries allow the reversal of chemical reactions through charging.

  • Lead-Acid Battery: Common in cars. Uses lead and lead dioxide in sulfuric acid.
  • Nickel-Cadmium (Ni-Cd): Rechargeable, long life, but environmentally hazardous.
  • Lithium-Ion: High energy density; used in smartphones, laptops, and EVs.

Applications: Electric vehicles, mobile devices, UPS systems

3. Fuel Cells

Fuel cells generate electricity through the continuous supply of fuel (typically hydrogen) and oxygen.

Reaction: H₂ + O₂ → H₂O + Electricity

Applications: Spacecraft, hydrogen-powered vehicles, power backups

How Does a Battery Work?

  1. Oxidation occurs at the anode, releasing electrons.
  2. Electrons flow through the external circuit, generating electric current.
  3. Reduction occurs at the cathode, where electrons are accepted.
  4. Ions in the electrolyte flow to maintain charge balance.

Key Electrochemistry Terms

  • Voltage (V): The potential difference between two electrodes
  • Capacity (mAh): How much charge the battery can store
  • Cycle Life: Number of complete charge-discharge cycles before degradation

The Future of Battery Technology

  • Solid-state Batteries: Safer, more compact, longer life
  • Graphene Batteries: Extremely fast charging and high capacity
  • Sodium-ion Batteries: Low-cost alternative to lithium-ion batteries

Summary: Battery Types at a Glance

TypeRechargeableEnergy DensityCommon Uses
Primary Battery❌ NoModerateRemotes, clocks
Secondary Battery✅ YesHighMobiles, EVs
Fuel Cell✅ YesVery HighEVs, backup power

Batteries are the powerful bridge between chemistry and the digital world.

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