IUPAC Nomenclature | Rules, Examples, Quiz

IUPAC Nomenclature

IUPAC Nomenclature is the standard system of naming chemical compounds as per the International Union of Pure and Applied Chemistry (IUPAC). It ensures a universal language among chemists worldwide.

Table of Contents

Why Is Nomenclature Important?

  • Provides unique identification of compounds.
  • Ensures global understanding of molecular structures.
  • Helps in interpreting chemical reactions correctly.

Basic Components of IUPAC Naming

A systematic name has:

  • Prefix – side chains/substituents
  • Word Root – number of carbon atoms
  • Primary Suffix – saturation/unsaturation (-ane, -ene, -yne)
  • Secondary Suffix – functional groups (-ol, -al, -oic acid)

Rules for IUPAC Naming

  1. Find the longest carbon chain (parent chain).
  2. Number carbons from nearest functional group.
  3. Name substituents as prefixes.
  4. Assign locants (position numbers).
  5. Combine prefix + root + suffix.

Examples

  • CH4 → Methane
  • CH3CH2CH3 → Propane
  • CH3CH=CH2 → Prop-1-ene
  • CH3CH(OH)CH3 → Propan-2-ol
  • CH3COOH → Ethanoic acid

Functional Group Suffix Table

Functional GroupFormulaSuffixExample
Alcohol-OH-olEthanol
Aldehyde-CHO-alEthanal
Ketone>C=O-onePropanone
Carboxylic Acid-COOH-oic acidEthanoic acid

Mnemonic Tips

Carbon chain roots: Meth, Eth, Prop, But, Pent, Hex, Hept, Oct, Non, Dec.

Quiz & Practice

MCQs

  1. The IUPAC name of CH3CH2OH is:
    A) Methanol
    B) Ethanol ✅
    C) Propanol
    D) Butanol
  2. The suffix “-oic acid” represents:
    A) Alcohol
    B) Ketone
    C) Carboxylic acid ✅
    D) Aldehyde

Fill in the Blanks

1. CH3CHO is called ________. (Answer: Ethanal)

2. The root word for 6 carbons is ________. (Answer: Hex-)

True/False

1. The root “But-” represents 5 carbons. ❌ (False, it’s 4 carbons)

2. Ketones use the suffix “-one”. ✅ (True)

Matching

CompoundSuffix
Alcohol-ol
Aldehyde-al
Ketone-one
Carboxylic acid-oic acid

FAQs

Q1: What is IUPAC nomenclature?
Ans: It is the universal system of naming chemical compounds developed by IUPAC.

Q2: Why is it important?
Ans: It avoids confusion and ensures international clarity in chemistry.

Q3: What is the root name for 7 carbons?
Ans: Hept-

हिंदी अनुभाग

IUPAC नामकरण रसायनों को नाम देने की एक वैज्ञानिक प्रणाली है। यह वैश्विक स्तर पर एकरूपता बनाए रखती है।

  • उदाहरण: CH4 = मीथेन
  • CH3CH2OH = एथेनॉल

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